Journal
JOURNAL OF POWER SOURCES
Volume 431, Issue -, Pages 259-264Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2019.05.059
Keywords
Bimetallic catalyst; Electrocatalyst; Pd-Ni bimetal; Direct urea/urine fuel cell (DUFC); Co-sputtering
Funding
- Agency for Defense Development [UD160050BD]
- Ocean University of China-Auburn University (OUC-AU)
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A solid solution Pd-Ni alloy co-sputtered on carbon paper (Pd-Ni/C) is explored as a catalyst in the flow-through porous anode of a direct urea fuel cell (DUFC). The catalytic performances of urea electro-oxidation in an alkaline medium are investigated by cyclic voltammetry and chronoamperometry. In order to minimize the effect of morphological variation by the Pd-Ni composition, the island structure with a uniform size or electrochemical surface area was prepared. The Pd-Ni/C electrode shows a much higher electrocatalytic activity and lower onset oxidation potential toward urea electro-oxidation compared to the Ag-Ni/C and Pt-Ni/C electrodes prepared by the same procedure. When the DUFC with a cell configuration of Pd-Ni/C anode and Pd/C cathode operates at room temperature, an open circuit voltage of 0.59 V was obtained with 0.33 molL(-1) urea solution as anolyte and humidification oxygen as the catholyte. The DUFC also exhibits a maximum power density of 1.12 mWcm(-2). The electrocatalytic activity by the developed solid solution is largely attributed to high intrinsic electronic conductivity, excellent porous network structures and a synergetic effect by the constituting bimetallic elements. This work develops a simple type of anode catalyst for DUFC, which can possibly open a promising approach for urea-rich wastewater treatment.
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