Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 123, Issue 33, Pages 20342-20350Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.9b05167
Keywords
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Funding
- National Natural Science Foundation of China [U1832203, 51671170, U1532115, 51671169]
- National Key Research and Development Program of China [2016YFB0701203, 2017YFA0403400, 2016YFB0700201]
- NSF of Zhejiang Province [Z1110196, Y4110192, LY15E010003]
- Fundamental Research Funds for the Central Universities
- Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund (the second phase) [U1501501]
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Temperature-induced liquid-liquid phase transition (LLPT) and pressure induced amorphous-amorphous phase transition (AAPT) have never been simultaneously reported in any single metallic system. In an Au55Cu25Si20 alloy, however, we discovered a temperature-induced LLPT by detecting reversible lambda-anomalies of the thermal expansion coefficient between two liquid states at ambient pressure, while a pressure-induced AAPT in Au55Cu25Si20 metallic glass (MG) occurs upon compression at ambient temperature. Both LLPT and AAPT are reversible with a hysteresis in temperature and pressure, respectively. Using molecular dynamics simulations and synchrotron X-ray techniques, we elucidate structural differences in both low- and high-pressure Au55Cu25Si20 MG phases and low- and high temperature Au55Cu25Si20 liquid phases. Electronic transfer between Si and Au or/and Cu atoms occurs in both temperature-induced LLPT and pressure-induced AAPT in the Au55Cu25Si20 alloy.
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