Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 902, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2019.120956
Keywords
o-carborane; B-H activation; Methylation; Selectivity
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Funding
- National Natural Science Foundation of China [21602182]
- Longshan academic talent research supporting program of SWUST [17LZX324, 18LZX305, 18LZXT02]
- Project of State Key Laboratory of Environment-friendly Energy Materials, SWUST [17fksy0102, 18fksy0206]
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The palladium catalyzed/counter ion tuned selective methylation of 9-amide-o-carboranes on B(4) and B(12) has been developed, and a series of o-carborane derivatives decorated with various groups have been synthesized with moderate yields. The in situ formed palladium species via counter ion exchange was proposed for the tunable B-H activation. (C) 2019 Elsevier B.V. All rights reserved.
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