Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 17, Pages 11316-11322Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b01753
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Funding
- ERC [716136]
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) [408033718]
- European Research Council (ERC) [716136] Funding Source: European Research Council (ERC)
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Metal-free N-H functionalization reactions represent an important strategy for sustainable C-N coupling reactions. In this report, we describe the visible light photolysis of aryl diazoacetates in the presence of some N-heterocycles that enables mild, metal-free N-H functionalization reactions of carbazole and azepine heterocycles (15 examples, up to 83% yield).
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