Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 18, Pages 12192-12197Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b01877
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Funding
- National Natural Science Foundation of China [21778025, 21762021]
- Science and Technology Project of Jiangxi Provincial Education Department [GJJ150297, GJJ150324]
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( )A highly efficient palladium-catalyzed Sonoga-shira coupling of benzylic ammonium salts with terminal alkynes is developed. This strategy provides a facile access to a series of internal alkyne derivatives in moderate to excellent yields via C-N bond cleavage and C(sp(3))-C(sp) bond formation. The broad substrate scope and high functional group tolerance make this reaction attractive for organic synthesis.
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