Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 19, Pages 12324-12333Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b01626
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Funding
- National Natural Science Foundation of China [21772137, 21542015, 21672157]
- PAPD
- project of scientific and technologic infrastructure of Suzhou [SZS201708]
- Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions [16KJA150002]
- Soochow University
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A visible light-induced Co- or Cu-catalyzed selenosulfonylation of alkynes for the synthesis of beta-(seleno)vinyl sulfones is demonstrated. This method utilizes a low-cost cobalt salt or metal copper as the catalysts. The reaction goes through a photoinduced free radical addition of selenosulfonates to alkynes for the 1,2-selenosulfonylation of alkynes under mild conditions.
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