Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 1189, Issue -, Pages 272-278Publisher
ELSEVIER
DOI: 10.1016/j.molstruc.2019.04.027
Keywords
1,10-Phenanthroline; 1,4-Dimethylpiperazine; 1,4-Butane sultone; Heteropoly acid; Ionic liquid catalyst; Reusable catalyst; Esterification reaction
Categories
Funding
- Research Council of Yasouj University
Ask authors/readers for more resources
Three novel heteropolyanion-based Bronsted acidic ionic liquids (BAILs), butane mono sulfoacid-functionalized 1,10-phenanthrolinum, butane mono and bis sulfoacid-functionalized 1,4-dimethylpiperazinium salts of phosphortungstate catalyst (PhBs(1)-PW, [PipBs(1)](3)-PW and [PipBs(2)](3)-(PW)(2)) were synthesized and well characterized with FTIR, H-1 and C-13 NMR, Electro-Spray Ionization Mass Spectrometry (ESI-MS), Elemental analysis (CHNS), EDX and TG analysis techniques. The esterification reactions of monocarboxylic acids with monohydric alcohols were carried out using these catalysts. The introduced catalysts present a self-separation performance after reaction, which can be easily recovered and quite steadily reused as confirmed by six-run recycling test. Moreover, bis sulfoacidfunctionalized 1,4-dimethylpiperazinium salt of phosphortungstate showed the best catalytic performance among the prepared catalysts for the esterification reaction. (C) 2019 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available