4.7 Article

Static and cyclic oxidation of Nb-Cr-V-W-Ta high entropy alloy in air from 600 to 1400 °C

Journal

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
Volume 38, Issue -, Pages 189-196

Publisher

JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2019.09.005

Keywords

High entropy alloys; Nb-Cr-V-W-Ta; Microstructures; Oxidation

Funding

  1. National Science Foundation
  2. NSF-PREM grant [DMR-1827745]

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An oxidation resistance study has been made on Nb-Cr-V-W-Ta high entropy alloy in a range of temperature from 600 to 1400 degrees C in air. Static oxidation study has been performed for either (a) 12 or 24h of heating time or (b) 3 or 10 degrees C/min heating rates to the desired oxidation temperature. Cyclic oxidation study conducted for three and a half days has been conducted at 600, 700, and 800 degrees C using 12 h of heating cycles. The alloy can withstand the cyclic oxidation process with only a reasonable loss of alloy. The identification of oxides indicates crystals of W and Ta oxides in cylindrical form while Nb and Cr oxides show a nodular or granular morphology at both 1000 and 1200 degrees C while and additional of oxide of V in whisker forms at 1200 degrees C. (C) 2019 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

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