Journal
JOURNAL OF CRYSTAL GROWTH
Volume 519, Issue -, Pages 54-59Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jcrysgro.2019.05.007
Keywords
Crystal structure; Growth from solutions; Borates; Rare earth compounds; Harmonic generators
Funding
- RFBR [18-32-20001]
- RSF [19-42-02003, IRN AP05130794]
- IGM SB RAS
- Russian Science Foundation [19-42-02003] Funding Source: Russian Science Foundation
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Non-centrosymmetric borates K7CaR2(B5O10)(3) have been synthesized by solid state reaction and successfully grown by the top seeded solution growth method using K2O-B2O3-CaF2 flux. IR, Raman, absorption spectra as well as data on melting temperature for the crystals were obtained. Optical properties like UV absorption edge and SHG intensity were compared with KH2PO4 (KDP) and K7CaY2(B5O10)(3).
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