Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 44, Issue 43, Pages 23868-23879Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2019.07.121
Keywords
Zn0.2Cd0.8S solid solutions; Photocatalyst; Visible-light- driven; H-2 production; 3D hierarchical
Categories
Funding
- National Natural Science Foundation of China [51772178, 21701107]
- Doctoral Scientific Research Startup Foundation of Shaanxi University of Science and Technology [2016QNBT-07]
- Platform Construction Fund for Imported Talents of Shaanxi University of Science Technology [134080038]
- State Key Laboratory of Solidification Processing in NWPU [SKLSP201729]
- Serve Local Special Projects of Shaanxi Provincial Department of Education [17JF004]
- China Postdoctoral Science Foundation [2016M592737]
Ask authors/readers for more resources
Nanorod assembled three-dimensional (3D) hierarchical Zn0.2Cd0.8S microspheres were successfully prepared by a facile one-pot microwave hydrothermal approach using ethylenediamine (EN) as a template agent. The optimal 3D hierarchical Zn0.2Cd0.8S microspheres (ZCS-30) is obtained when adding 30 mL into the synthetic system, which can function as a highly active photocatalyst for H-2 evolution under visible-light irradiation with the wavelength of 420 nm, delivering an activity approximately 2.5 and 7.5 times higher than that of Zn0.2Cd0.8S nanoparticles and CdS counterparts, respectively, and giving an apparent quantum efficiency (AQE) of 7.4%. Furthermore, the ZCS-30 photocatalyst shows the good stability after the catalytic H-2 evolution for 15 h (5 cycles). In addition, the ZCS-30 photocatalyst exhibits the excellent degradation of Rhodamine B (Rh B) almost up to 80% under the visible light irradiation over a period of 150 min. The results demonstrate that ZCS-30 can serve as a promising visible-light-driven bifunctional photocatalyst for water splitting and dye degradation. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available