Journal
INORGANIC CHEMISTRY
Volume 58, Issue 17, Pages 11284-11288Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b02104
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Funding
- Japan Society for the Promotion of Science (JSPS) [24245011, 17H03027, 15J04635]
- JSPS by Leading Initiative for Excellent Young Researchers (LEADER)
- Grants-in-Aid for Scientific Research [17H03027, 15J04635] Funding Source: KAKEN
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We have designed and synthesized a hetero-dinuclear Ru-II-Co-II complex with a dinucleating ligand inspired by hetero-dinuclear active sites of metalloenzymes. A synergistic effect between the adjacent Ru-II and Co-II sites has been confirmed in catalytic olefin hydrogenation by the complex, exhibiting a much higher turnover number than those of mononuclear Ru-II or Co-II complexes as the components. A Ru-II-hydrido species was detected by H-1 NMR and electrospray ionization (ESI)-time-of-flight (TOF)-MS measurements as an intermediate to react with olefins, and Co-II-bound methanol was suggested to act as a proton source.
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