Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 58, Issue 38, Pages 17660-17667Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.9b03138
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Funding
- National Natural Science Foundation of China [21372147]
- Undergraduate Innovative Research Training Program of SDNU [201810445391]
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A carboxy-functionalized covalent organic framework COOH@COF for efficient removal of Pb2+ and Hg2+ ions from water has been prepared. Fourier transform infrared spectroscopy, solid-state C-13 NMR spectra, and elemental analysis indicate that the carboxy function has been grafted to COF materials via the click reaction. Its crystallinity remains unchanged after post-synthetic modification, as confirmed by the powder X-ray diffraction. Scanning electron microscopy images reveal that the COOH@COF possesses the thorn ball structure assembled by numerous nanowires with a diameter of 90 nm. This COOH@COF features excellent adsorption capacities for Pb2+ (123.8) and Hg2+ (99.1 mg/g) in water. The adsorption isotherms follow the Langmuir model, and their kinetics adsorption fits the pseudo-second-order model. Particularly, the COOH@COF can be recycled 20 times without loss of the adsorption capacity in water, showing its latent potential for practical application in the future.
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