Journal
GEOSTANDARDS AND GEOANALYTICAL RESEARCH
Volume 44, Issue 1, Pages 57-67Publisher
WILEY
DOI: 10.1111/ggr.12295
Keywords
lithium isotopes; automated ion-exchange chromatography; MC-ICP-MS; reference materials; NASS-6; GS-N; NIST SRM 2709a; ChemCobOne
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Funding
- People Programme (Marie Curie Actions) of the European Union's Seventh Framework Programme FP7/2007-2013/ under REA grant [608069]
- CleanChemlab
- Region Ile-de-France
- IPGP multidisciplinary programme PARI
- Paris-IdF region SESAME Grant [12015903]
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The demand for large and reliable data sets on isotopic composition has increased in geochemistry and environmental sciences over recent years. We present an automated ion chromatographic separation method using a robotic pipetting arm, termed 'ChemCobOne', to reduce sample separation time. Its performance was tested for lithium isotope separation in geological reference materials using a single-step separation with HCl (0.2 mol l(-1)) and a 2 ml resin volume. This refined lithium purification method does not forfeit precision, accuracy or purity compared with manual sample processing. In addition, a delta Li-7 value for NASS-6 of 30.99 +/- 0.50 parts per thousand (2s) (95% CI = 0.14 parts per thousand, n = 44) was determined and the first delta Li-7 values for the granite rock reference material GS-N (-0.57 +/- 0.25 parts per thousand (2s), 95% CI = 0.15 parts per thousand, n = 15), and for the soil reference material NIST SRM 2709a (-0.37 +/- 0.67 parts per thousand (2s), 95% CI = 0.15 parts per thousand, n = 63) are proposed.
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