Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2019, Issue 36, Pages 6163-6167Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201900726
Keywords
Cleavage reactions; Diols; Oxidation; Silanes; Synthetic methods
Categories
Funding
- Deutsche Forschungsgemeinschaft [ME 776/20-2]
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We report a study on diol cleavage of cyclic 1,2-dihydroxysilanes for the preparation of functionalized acylsilanes. Sodium periodate turned out to be an efficient reagent for this transformation, resulting in good to excellent yields. The method is characterized by mild reaction conditions, and sometimes simple aqueous workup of the reaction mixture was sufficient to obtain the acylsilanes in high purity. An acyclic 1,2-dihydroxysilane was readily cleaved as well.
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