Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2020, Issue 10, Pages 1559-1566Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201901063
Keywords
Trifluoromethylselenolation; Acridinium; Photochemistry; Alkylsilanes; Potassium alkyltrifluoroborates; Reaction mechanisms
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Funding
- la region Rhone Alpes
- federation RENARD
- Departement de Chimie Moleculaire, Universite Grenoble Alpes
- CNRS, ICBMS (UMR 5246), ICL (Institut de Chimie de Lyon)
- French Fluorine Network
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Herein a metal-free fluoroalkylselenolation of alkylsilanes as well as potassium alkyltrifluoroborates under visible light photocatalysis is disclosed. The developed methodologies are performed under mild conditions, room temperature in the presence of an organic photocatalyst and blue LED irradiation. Mechanistic investigations including luminescence and EPR spectroscopy allow us to shed light on both mechanisms.
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