Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2020, Issue 10, Pages 1478-1481Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201901157
Keywords
Atropselective photoreactions; Photochirogenesis; Asymmetric photochemistry; Chiral photochemistry; Energy transfer catalysis
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Funding
- National Science Foundation [CHE-1811795]
- BGSU
- center for photochemical Sciences
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Intermolecular [2+2]-photocycloaddition of atropisomeric phenyl maleimide has been evaluated with substituted alkenes with complete control over regiochemistry. We were also successful in carrying out atropselective reactions with the removal of axial chirality leading to enantio-enriched photoproducts. Based on detailed photophysical studies, a mechanistic rationale is proposed for the observed selectivity.
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