Enhanced peroxidase-like activity of hierarchical MoS2 -decorated N-doped carbon nanotubes with synergetic effect for colorimetric detection of H2O2 and ascorbic acid

The exploitation of multifunctional nanocomposites is highly desired in environmental monitoring, biosensors, and medical diagnosis. In this paper, a simple approach has been proposed to fabricate MoS2 decorated N-doped carbon nanotubes (NCNTs@MoS2) hybrid composites as efficient peroxidase-like mimics. The combination of the MoS2 and N-doped carbon nanotubes (NCNTs) brings about an enhanced synergistic effect, leading to remarkably decent intrinsic peroxidase-mimic activities than that of the single components. Due to the high catalytic efficiency of the resultant NCNTs@MoS2 hybrid nanotubes as peroxidase-like mimics, a convenient colorimetric approach for the sensitive determination of H2O2 and ascorbic acid have been developed with a detection limit of about 0.141 mu mol/L and 0.121 mu mol/L, respectively. The work offers a new strategy for the fabrication of peroxidase-like nanomaterials with excellent catalytic activity, which indicates great promising applications in sensitive detections in real samples. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.