4.7 Review

Recent progress in transition metal catalyzed cross coupling of nitroarenes

Journal

CHINESE CHEMICAL LETTERS
Volume 30, Issue 8, Pages 1481-1487

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2019.04.008

Keywords

Transition metal; Catalysis; Nitroarenes; Cross coupling; Chemical bonds

Funding

  1. National Natural Science Foundation of China [21802040, 21877034]
  2. Natural Science Fund Youth Project of Hunan Province [2018113145]
  3. General project of Hunan Education Department [17C0629]
  4. Open Foundation of Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education, Hunan University of Science and Technology [E21843]

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In this review, the recent development in transition metal catalyzed cross coupling of nitroarenes was highlighted. Firstly, development of transition metal catalyzed cross coupling was simply introduced. After presenting the advantages of nitroarenes, transition metal catalyzed cross coupling using nitroarenes as electrophilic coupling partners was classified and introduced in detail. Based on different chemical bonds such as C-O, C-S, C-C and C-N bonds constructed, different kinds cross coupling of nitroarenes would be highlighted and the plausible reaction mechanism would be presented if available. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

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