4.6 Article

Porous Cationic Covalent Triazine-Based Frameworks as Platforms for Efficient CO2 and Iodine Capture

Journal

CHEMISTRY-AN ASIAN JOURNAL
Volume 14, Issue 19, Pages 3259-3263

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201901017

Keywords

cationic frameworks; iodine capture; imidazolium tectons; porous organic polymers

Funding

  1. Science and Technology Program of Jilin Province [20180520154JH, 20180520152JH]
  2. Science and Technology Plan Funds of Siping City, China [2017090, 2017092]

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Porous cationic covalent triazine-based frameworks (CTFs) with imidazolium salts as tectons were prepared via ionothermal synthesis. The high-PF6--content CTF shows the CO2 adsorption of 44.7 cm(3) g(-1) and I-2 capture capacity of 312 wt %. The influence of counterion species and contents on the porosities, CO2 adsorptions, and I-2 capture capacities of the CTFs has been investigated.

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