Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 14, Issue 24, Pages 4557-4562Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201900908
Keywords
acetalization; alcohols; aldehydes; homogeneous catalysis; nickel
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Funding
- SERB, India [CRG/2018/002480/OC]
- UGC, India
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A molecularly defined Ni-II-complex catalyzing the chemoselective acetalization of aldehydes with alcohols under neutral conditions is reported. The reaction is general, efficient and showed a wide substrate scope (including aliphatic aldehydes) as well as excellent functional group tolerance. Reusability of the present nickel catalyst is also demonstrated.
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