4.6 Article

Nickel-Catalyzed Chemoselective Acetalization of Aldehydes With Alcohols under Neutral Conditions

Journal

CHEMISTRY-AN ASIAN JOURNAL
Volume 14, Issue 24, Pages 4557-4562

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201900908

Keywords

acetalization; alcohols; aldehydes; homogeneous catalysis; nickel

Funding

  1. SERB, India [CRG/2018/002480/OC]
  2. UGC, India

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A molecularly defined Ni-II-complex catalyzing the chemoselective acetalization of aldehydes with alcohols under neutral conditions is reported. The reaction is general, efficient and showed a wide substrate scope (including aliphatic aldehydes) as well as excellent functional group tolerance. Reusability of the present nickel catalyst is also demonstrated.

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