Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 25, Issue 59, Pages 13504-13508Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201903625
Keywords
acrylic acid; carbon dioxide; NHC; nickel; nickelalactone
Categories
Funding
- Japan Science and Technology Agency [JPMJCR12Y3] Funding Source: Medline
- Japan Society for the Promotion of Science [15H05800,17H06143] Funding Source: Medline
Ask authors/readers for more resources
By using a nickel complex with an N-phosphinomethyl-N-heterocyclic carbene ligand (NHC-P), the reducing ability and thermal stability of the complex were improved considerably compared to the previously reported bipyridine and bisphosphine complexes, and acrylate salt was prepared from ethylene and CO2 with the highest TON ever reported for nickel systems even without using metallic zinc. Oxidative cyclization of ethylene and CO2 on the NHC-P nickel complex was found to proceed very rapidly compared to previous systems.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available