4.7 Article

Atomic layer deposited YSZ overlayer on Ru for direct methane utilization in solid oxide fuel cell

Journal

CERAMICS INTERNATIONAL
Volume 46, Issue 2, Pages 1705-1710

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2019.09.143

Keywords

Solid oxide fuel cell; Atomic layer deposition; Methane oxidation; Ruthenium; Yttria-stabilized zirconia

Funding

  1. Seoul National University of Science and Technology (SeoulTech) [2019-0364]

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We report on the fabrication of thin yttria-stabilized zirconia (YSZ) overlayers via atomic layer deposition (ALD) conformally coated on anodes of methane-fueled low-temperature solid oxide fuel cells. Nano-granular ALD YSZ overlayers that are broken into porous films at elevated temperature improved not only the initial electrochemical performance (35% increase in the maximum power density) but also the thermal stability of the porous Ru anodes by suppressing coarsening.

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