Journal
CARBON
Volume 149, Issue -, Pages 538-545Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2019.04.076
Keywords
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Funding
- National Natural Science Foundation of China [51622805, U1633116]
- opening fund for the subject of Transportation Engineering in Tongji University [2016J012306]
- Research Project of Yunan Department of Transportation [2016(A)16]
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The development of simple and feasible methods to synthesize highly efficient adsorbents is the key to low-cost gas purification. Here we developed an in-situ amorphous cobalt template method based on the synergistic effect of precursor to synthesize nitrogen doped unimodal ultramicropores carbon nanosheets Co-NDPCs with high nitrogen content (up to 11.74%), large specific surface area (up to 1187 m(2) g(-1)) and unimodal ultramicropore. As an adsorbent, the Co-NDPCs exhibit unprecedented C2H2, C2H6, C3H8 and CO2 uptake capacities of 6.7, 5.9, 7.4 and 5.6 mmol g(-1), respectively, and the corresponding x/CH4 and CO2/N-2 IAST selectivities are as high as 75.3, 65.9.1743.6, 11.4 and 74.7 at 298 K and 1 bar. More importantly, this method effectively avoids the defects of traditional activation or template method, such as corrosiveness, poor safety and complicated process, indicating that Co-NDPCs is a promising adsorbent for CH4/C2H2/C2H6/C3H8/CO2/N-2 capture and separation. (C) 2019 Elsevier Ltd. All rights reserved.
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