Journal
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY
Volume 83, Issue 12, Pages 2198-2201Publisher
OXFORD UNIV PRESS
DOI: 10.1080/09168451.2019.1654850
Keywords
Phorbasins; absolute configuration; enantioselective synthesis; marine natural product
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The first synthesis of phorbasin H, a diterpene carboxylic acid isolated from the sponge Phorbas gukulensis, was achieved using 1,4-trans-cyclohexanedimethanol and (S)-citronellal as starting materials. The data collected in this synthesis indicated the absolute configuration of the naturally occurring phorbasin H to be S.
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