Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 361, Issue 19, Pages 4568-4574Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201900975
Keywords
Free-Radical; C-C Bond Cleavage; Alcohols; Sugars; C-H Alkylation; C-H Acylation
Categories
Funding
- National Natural Science Foundation of China [21672089]
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We reported herein a predictable and surgical cleavage of carbon-carbon bond in alcohols. A wide range of 1 degrees, 2 degrees and 3 degrees alcohols including sugars and steroids without ring strain or steric hindrance were all compatible with this system. Also it offered a green and practical strategy for generation of alkyl/acyl radicals using alcohols as the sources. Besides, the features of visible-light-initiation, catalyst and metal free, excellent selectivity and mild conditions make it valuable and attractive.
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