Journal
ADVANCED MATERIALS
Volume 31, Issue 50, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201902029
Keywords
high-voltage compatibility; intermolecular interaction; ionic conductivity; polymer electrolytes; solid lithium batteries
Categories
Funding
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDA22000000]
- Youth Innovation Promotion Association of CAS [2016193]
- National Key R&D Program of China [2018YFB0104300]
- National Natural Science Foundation for Distinguished Young Scholars of China [51625204]
- Key research and development plan of Shandong Province [2018GGX104016]
- Key Scientific and Technological Innovation Project of Shandong [2017CXZC0505]
- Qingdao Post-doctoral Applied Research Project
- Think-Tank Mutual Fund of Qingdao Energy Storage Industry Scientific Research
- 135 Projects Fund of CAS-QIBEBT Director Innovation Foundation
- Qingdao Science and Technology Program [17-1-1-26-jch]
- NSFC-Shandong Joint Fund [U1706229]
- Shandong Natural Science Foundation [ZR2018ZB0316]
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Solid polymer electrolytes (SPEs) have aroused wide interest in lithium batteries because of their sufficient mechanical properties, superior safety performances, and excellent processability. However, ionic conductivity and high-voltage compatibility of SPEs are still yet to meet the requirement of future energy-storage systems, representing significant barriers to progress. In this regard, intermolecular interactions in SPEs have attracted attention, and they can significantly impact on the Li+ motion and frontier orbital energy level of SPEs. Recent advances in improving electrochemcial performance of SPEs are reviewed, and the underlying mechanism of these proposed strategies related to intermolecular interaction is discussed, including ion-dipole, hydrogen bonds, pi-pi stacking, and Lewis acid-base interactions. It is hoped that this review can inspire a deeper consideration on this critical issue, which can pave new pathway to improve ionic conductivity and high-voltage performance of SPEs.
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