Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 29, Issue 39, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201904856
Keywords
dopant-free; hole-transporting; perovskite solar cells; polymers; side chains
Categories
Funding
- Ministry of Science and Technology of the People's Republic of China [2016YFA0202400, 2016YFA0202404]
- Peacock Team Project funding from Shenzhen Science and Technology Innovation Committee [KQTD2015033110182370]
- Shenzhen Development and Reform Committee [2019-126]
- Shenzhen Science and Technology Innovation Committee [JCYJ20180302174321291]
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A variety of dopant-free hole-transporting materials (HTMs) is developed to serve as alternatives to the typical dopant-treated ones; however, their photovoltaic performance still falls far behind. In this work, the side chain of a polymeric HTM is engineered by partially introducing diethylene glycol (DEG) groups in order to simultaneously optimize the properties of both the bulk of the HTM layer and the HTM/perovskite interface. The intermolecular pi-pi stacking interaction in the HTM layer is unexpectedly weakened after the incorporation of DEG groups, whereas the lamellar packing interaction is strengthened. A doubled hole mobility is obtained when 3% of the DEG groups replace the original alkyl side chains, and a champion power conversion efficiency (PCE) of 20.19% (certified: 20.10%) is then achieved, which is the first report of values over 20% for dopant-free organic HTMs. The device maintains 92.25% of its initial PCE after storing at ambient atmosphere for 30 d, which should be due to the enhanced hydrophobicity of the HTM film.
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