Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 29, Issue 45, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201904684
Keywords
general method; hypocrystalline intermediate; organic solar cells; perovskite solar cells; ternary metal oxide nanoparticles
Categories
Funding
- University Grant Council (UGC) of the University of Hong Kong [201711159074, 201811159147]
- General Research Fund from the Research Grants Council of Hong Kong Special Administrative Region, China [17204117, 17200518, 17201819]
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Solution-process fine metal-oxide nanoparticles are promising carrier transport layer candidates for unlocking the full potential of solution process in solar cells, due to their low cost, good stability, and favorable electrical/optical properties. However, exotic organic ligands adopted for achieving small size and monodispersion can mostly cause poor conductivity, which thus impedes their electrical application. In this work, a concept of constructing a hypocrystalline intermediate is proposed to develop a general method for synthesizing various ternary metal oxide (TMO) nanoparticles with a sub-ten-nanometer size and good dispersibility without exotic ligands. Particularly, a guideline is summarized based on the understandings about the impact of metal ion intercalation as well as water and anion coordination on the hypocrystalline intermediate. A general method based on the proposed concept is developed to successfully synthesize various sub-ten-nanometer TMO nanoparticles with excellent ability for forming high-quality (smooth and well-coverage) films. As an application example, the high-quality films are used as hole transport layers for achieving high-performance (stability and efficiency) organic/perovskite solar cells. Consequently, this work will contribute to the development of TMO for large-scale and high-performance optoelectronic devices and the concept of tailoring intermediate can leverage the fundamental understandings of synthesis strategies for other metal oxides.
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