Emergence of shallow energy levels in B-doped Q-carbon: A high-temperature superconductor

We report the spectroscopic demonstration of the shallow-level energy states in the recently discovered B-doped Q-carbon Bardeen-Cooper-Schrieffer (BCS) high-temperature superconductor. The Q-carbon is synthesized by ultrafast melting and quenching, allowing for high B-doping concentrations which increase the superconducting transition temperature (T-c) to 36 K (compared to 4 K for B-doped diamond). The increase in T-c is attributed to the increased density of energy states near the Fermi level in B-doped Q-carbon, which give rise to superconducting states via strong electron-phonon coupling below T-c. These shallow-level energy states, however, are challenging to map due to limited spatial and energy resolution. Here, we use ultrahigh energy resolution monochromated electron energy-loss spectroscopy (EELS), to detect and visualize the newly formed shallow-level energy states (vibrational modes) near the Fermi level (ranging 30-100 meV) of the B-doped Q-carbon. With this study, we establish the significance of high-resolution EELS in understanding the superconducting behavior of BCS superconducting C-based materials, which demonstrate a phenomenal enhancement in the presence of shallow-level energy states. (C) 2019 Published by Elsevier Ltd on behalf of Acta Materialia Inc.