4.8 Article

Investigation of the Mechanism for Ohmic Contact Formation in Ti/Al/Ni/Au Contacts to β-Ga2O3 Nanobelt Field-Effect Transistors

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 11, Issue 35, Pages 32127-32134

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b09166

Keywords

wide-bandgap semiconductors; gallium oxide; field-effect transistors; Ohmic contact; multilayer metal stack; oxygen vacancies

Funding

  1. National Key R&D Program of China [2016YFE0110700]
  2. National Natural Science Foundation of China [U1632121, 11804055, 51861135105, 61874034]
  3. Natural Science Foundation of Shanghai [18ZR1405000]

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The issue of contacts between the electrode and channel layer is crucial for wide-bandgap semiconductors, especially the beta-Ga2O3 due to its ultra-large bandgap (4.6-4.9 eV). It affects the device performance greatly and thus needs special attention. In this work, the high-performance beta-Ga2O3 nanobelt field-effect transistors with Ohmic contact between multilayer metal stack Ti/Al/Ni/Au (30/120/50/50 nm) and unintentionally doped beta-Ga2O3 channel substrate have been fabricated. The formation mechanism of Ohmic contacts to beta-Ga2O3 under different annealing temperatures in an N-2 ambient is systematically investigated by X-ray photoelectron spectroscopy. It is revealed that the oxygen vacancies at the interface of beta-Ga2O3/intermetallic compounds formed during rapid thermal annealing are believed to induce the good Ohmic contacts with low resistance. The contact resistance (R-c) between electrodes and unintentionally doped beta-Ga2O3 reduces to, similar to 9.3 Omega mm after annealing. This work points to the importance of contact engineering for future improved beta-Ga2O3 device performance and lays a solid foundation for the wider application of beta-Ga2O3 in electronics and optoelectronics.

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