4.0 Article

Cooperative Stereocontrol by Proximal and Distal Chlorine Substituents in the Chiral Lewis Base-catalyzed Kinetic Resolution of cis-Vinyl Epoxide

Journal

BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 40, Issue 8, Pages 835-838

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/bkcs.11829

Keywords

Vinyl epoxide; Kinetic resolution; Lewis base catalysis; Epoxide opening; Chlorine

Funding

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [NRF-2015R1C1A1A01055755]

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Mechanistic study on the stereocontrolling role of chlorine substituents by control experiments and computational analysis.

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