Journal
ACS ENERGY LETTERS
Volume 4, Issue 7, Pages 1650-1657Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.9b00857
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Funding
- National Key Technologies R&D Program, China [2016YFB0901500]
- National Natural Science Foundation of China [51725206, 51421002, 51822211]
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Solid polymer electrolytes (SPEs) are considered as promising candidates for solid-state batteries. SPEs with a conventional solution casting technique have serious side reactions during charging because of the residual solvent. Here we report a creative method that can self-remove it via spontaneous reactions. The core idea is to consume the residual solvent and form stable products by choosing proper salt, solvent, and additives. Inspired by the hydrolysis of sodium bis(fluorosulfonyl)imide (NaFSI), during which the proton carrier changes from H2O to HF and HF further reacts with metal oxide to form a stable hydrate, like AlF3 center dot 6H(2)O, NaFSI, H2O, and Al2O3/SiO2 nanoparticles are thus employed to prepare poly(ethylene oxide) (PEO)-based SPEs. Solid-state sodium batteries with PEO/NaFSI-Al2O3-AQ electrolytes exhibit good reversibility with Na3V2(PO4)(3) as the active materials, high rate performance, long-term cycling stability (92.8% after 2000 cycle), and high Coulombic efficiency. Furthermore, environmentally friendly and low-cost preparation of PEO-based SPEs is realized with this aqueous technique.
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