Journal
ACS ENERGY LETTERS
Volume 4, Issue 7, Pages 1572-1578Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.9b00793
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Funding
- PRESTO program from the Japan Science and Technology Agency (JST) [JPMJPR15N6]
- Japan Society for the Promotion of Science (JSPS) through a KAKENHI [JP16H02285]
- JST-CREST [JPMJCR1421]
- JSPS scholarship [JP18J01488]
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Owing to the shallow valence band maximum generated upon hybridization of Bi/Pb 6s and O 2p orbitals, layered oxyhalides of Bi4TaO8Cl and PbBiO2Cl are stable and promising O-2-evolving photocatalysts for Z-scheme water splitting. However, some questions remain regarding how their synthesis parameter influences the charge carrier dynamics and overall photocatalytic process. Here, we show that the product of the transient pseudophotoconductivity maximum (phi Sigma mu(max)) and half-lifetime (tau(1/2)), as evaluated by time-resolved microwave conductivity (TRMC) measurements, correlates well with the O-2 evolution rates of such oxyhalides. Such correlation in Bi4TaO8Cl is rationalized by the increased crystallite size and decreased Cl/Bi atomic ratio with the increasing calcination temperature. On the basis of this, we examined the processing temperature of the rarely studied PbBiO2Cl by TRMC analysis and demonstrate a 3-fold enhancement of its O-2 evolution rate (apparent quantum efficiency of 3%), which is among the best performances of oxyhalides prepared by a solid-state reaction. This study suggests that TRMC evaluation provides a facile means to examine the potential of semiconducting photocatalysts.
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