Journal
TOPICS IN CURRENT CHEMISTRY
Volume 377, Issue 4, Pages -Publisher
SPRINGER INTERNATIONAL PUBLISHING AG
DOI: 10.1007/s41061-019-0246-3
Keywords
Fused heteroaromatic rings; Cross-dehydrogenative coupling; C-H activation; Intramolecular oxidative cyclization; Lewis acids; Metal-mediated
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Funding
- Facultad de Farmacia (Universidad Central de Venezuela)
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The present review highlights the most important recent contributions toward the synthesis of functionalized fused heteroaromatic rings via intramolecular C-H activation mediated or catalyzed by transition metals. This type of reaction constitutes a versatile strategy to obtain a great variety of fused heterocyclic systems through the formation of carbon-carbon (C-C) and C-heteroatom bonds from direct coupling between two adjacent C-H bonds or C-H/H-X bonds. The revision is focused on the synthesis of fused heterocycles through two chemical processes: (1) metal-catalyzed intramolecular oxidative C-H activation, and (2) intramolecular C-H activation mediated by metallic Lewis acids.
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