Journal
SCIENCE BULLETIN
Volume 64, Issue 17, Pages 1280-1284Publisher
ELSEVIER
DOI: 10.1016/j.scib.2019.07.007
Keywords
Chalcogen; Organotellurium catalysis; Aerobic oxidation; Deoximation; Free radical; Tellurium
Categories
Funding
- National Key Research and Development Program of China [2018YFD0200100]
- Natural Science Foundation of Jiangsu Province [BK20181449]
- Zhejiang Provincial Natural Science Foundation [LY19B020004]
- Jiangsu Provincial Six Talent Peaks Project [XCL-090]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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Catalyzed by commercially available (PhTe)(2), molecular oxygen could be utilized as the mild, cheap and safe oxidant for oxidative deoximation reactions under solvent-free conditions. As the first report on organotellurium-catalyzed deoximation reaction, this work not only provides an efficient deoximation method, but also discloses new features of tellurium catalyst different from those of the organoselenium catalysts. (C) 2019 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
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