Journal
ACS CATALYSIS
Volume 9, Issue 7, Pages 5929-5934Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b00869
Keywords
single-atom catalysts; Fe-N; carbon nanowire; density functional theory; oxygen reduction
Categories
Funding
- National Key R&D Program of China [2017YFB0102900]
- Research Grant Council of the Hong Kong Special Administrative Region [N_HKUST610/17]
- Guangdong Special Fund for Science and Technology Development (Hong Kong Technology Cooperation Funding Scheme) [201704030019, 201704030065]
- Shenzhen Science and Technology Innovation Commission [JCYJ20180507183818040]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- NIU start-up fund
Ask authors/readers for more resources
The development of efficient Fe-N-C materials enriched with single-atom Fe sites toward the oxygen reduction reaction (ORR) is still a great challenge because Fe atoms are mobile and easily aggregate into nanoparticles during the high-temperature treatment. Herein, we proposed a facile and universal secondary-atom-assisted strategy to prepare atomic iron sites with high density hosted on porous nitrogen-doped carbon nanowires (Fe-NCNWs). The Fe-NCNWs showed an impressive half-wave potential (E-1/2) of 0.91 V and average kinetic current density (J(K)) of 6.0 mA cm(-2) at 0.9 V in alkaline media. They also held a high ORR activity in acidic solution with the E-1/2 of 0.82 V and average J(K) of 8.0 mA cm(-2) at 0.8 V. Density functional theory calculations demonstrated that the high ORR activity achieved is originated from single-atom iron sites that decrease the energy barrier in the reaction path efficiently.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available