Journal
ACS CATALYSIS
Volume 9, Issue 7, Pages 6583-6587Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b02005
Keywords
vinyl epoxides; borylation; copper catalysis; allylic alcohols; skipped dienes
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Funding
- European Research Council [ERC-337776]
- MINECO [CTQ2016-78779-R]
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We present an efficient strategy for the formal 1,4-reduction of vinyl epoxides that does not require superstoichiometric amounts of a strong reductant. Using a readily available copper catalyst and a diboron compound, a wide variety of enantioenriched allylic alcohols have been prepared. Additionally, epoxyenynes have been reduced in a 1,4-manner to selectively afford skipped enynes or skipped dienes.
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