Journal
TETRAHEDRON
Volume 75, Issue 24, Pages 3282-3291Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2019.04.050
Keywords
Privileged ligands; PHOX; Asymmetric catalysis; Aza-Michael
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Funding
- National Natural Science Foundation of China (NNSFC) [21772090, 21602052]
- 1000 Youth Talents Program of China
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Four newly designed CyPHOX ligands with chiral cyclohexane scaffold replacing the previous planar aryl group of PHOX ligands, were efficiently prepared. The synthesis features a kinetically controlled asymmetric phos-Michael reactions of trisubstituted cyclic carboxylates, which is quite simple, reliable and scalable. (C) 2019 Elsevier Ltd. All rights reserved.
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