Journal
SYNLETT
Volume 30, Issue 17, Pages 1954-1965Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1689924
Keywords
carbonyl-olefin metathesis; hydrazines; 1,3-dipolar cycloadditions; azomethine imines; cycloreversion
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Funding
- National Science Foundation [CHE-0953259]
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Carbonyl-olefin metathesis is a potentially powerful yet underexplored reaction in organic synthesis. In recent years, however, this situation has begun to change, most notably with the introduction of several different catalytic technologies. The development of one of those new strategies, based on hydrazine catalysts and a novel [3+2] paradigm for double bond metathesis, is discussed herein. First, the stage is set with a description of some potential applications of carbonyl-olefin metathesis and a discussion of alternative strategies for this intriguing reaction.
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