Journal
RUSSIAN CHEMICAL BULLETIN
Volume 68, Issue 6, Pages 1213-1218Publisher
SPRINGER
DOI: 10.1007/s11172-019-2543-y
Keywords
lithium 3-polyfluoroalkyl-1; 3-diketonates; lithium (Z)-1; 1; 1-trifluoro-4-oxo-4-(pyridinyl)but-2-en-2-olates; crystal structure; X-ray diffraction
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Funding
- [AAAA-A19-119012290117-6]
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Lithium 3-trifluoromethyl-1,3-diketonates containing pyridyl substituents were synthesized. The specific features of the crystal structures of lithium (Z)-1,1,1-trifluoro-4-oxo-4-(pyridin-3-yl)- and (Z)-1,1,1-trifluoro-4-oxo-4-(pyridin-4-yl)but-2-en-2-olates were revealed by X-ray diffraction. These compounds have a polymeric structure with lithium cations in different coordination modes. The 1,3-diketonate group is involved in chelation and formation of oxygen bridges, thereby linking two types of lithium atoms.
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