Rotational Instability in Superlubric Joints

Surface and interfacial energies play important roles in a number of instability phenomena in liquids and soft matter, but rarely have similar effects in solids. Here, a mechanical instability is reported which is controlled by surface and interfacial energies and is valid for a large class of materials, in particular two-dimensional layered materials. When sliding a top flake cleaved from a square microscale graphite mesa by using a probe acting on the flake through a point contact, it was observed that the flake moved unrotationally for a certain distance before it suddenly transferred to a rotating-moving state. The theoretical analysis was consistent with the experimental observation and revealed that this mechanical instability was an interesting effect of the structural superlubricity (a state of nearly zero friction). Further analysis showed that this type of instability was applicable generally for various sliding joints on different scales, as long as the friction was ultralow. Thus, the uncovered mechanism provides useful knowledge for manipulating and controlling these sliding joints, and can guide the design of future superlubricity-based devices.