Journal
ORGANIC PROCESS RESEARCH & DEVELOPMENT
Volume 23, Issue 8, Pages 1669-1673Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.oprd.9b00191
Keywords
multigram-scale synthesis; benzoxepines; coumarins; cycloadditions; Rh catalysis; C-H activation
Categories
Funding
- Spanish grants [SAF2016-76689-R, CTQ2016-77047-P]
- Spanish grants (Juan de la Cierva-Incorporation Fellowship) [IJCI-2017-31450]
- Conselleria de Cultura, Educacion e Ordenacion Universitaria [ED431C 2017/19, 2015-CP082]
- European Regional Development Fund (ERDF)
- European Research Council [340055]
- Conselleria de Cultura, Educacion e Ordenacion Universitaria (Centro Singular de Investigacion de Galicia Accreditation 2016-2019) [ED431G/09]
- orfeo-cinqa network [CTQ2016-81797REDC]
Ask authors/readers for more resources
Herein we disclose the assembly of benzoxepines and coumarins from 2-alkenylphenol precursors using [Cp*RhCl2](2) as the precatalyst and alkynes or carbon monoxide as reacting partners. The preparation of benzoxepines and coumarins can be scaled up to 33 mmol using low catalyst loadings.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
