Journal
ORGANIC LETTERS
Volume 21, Issue 16, Pages 6225-6230Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02051
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Funding
- NSFC [21702117, 21776148]
- Natural Science Foundation of Shandong Province [ZR2017BBOOS, ZR2016BM07]
- Key Research & Development Program of Shandong Province [2018GSF118224, 2019GGXI02036]
- Talents of High Level Scientific Research Foundation [6631115015, 6631110309, 6651118009]
- Central Laboratory of Qingdao Agricultural University
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The pharmaceutically intriguing spiroindolenines incorporating tetrahydroquinoline were constructed via a hexafluoroisopropanol-promoted redox-neutral cascade cyclization from readily available starting materials. The benzazepinoindole skeletons could also be facilely accessed via one-pot sequential operation. Distinctive features of these transformations include their controllable access of the two privileged skeletons, high efficiency, simple operation, and mild reaction conditions.
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