Journal
ORGANIC LETTERS
Volume 21, Issue 14, Pages 5462-5466Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01717
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Funding
- National Natural Science Foundation of China [21425415, 21774056]
- National Basic Research Program of China [2015CB856303]
- Science and Technology Department of Jiangsu Province [BRA2017360, BK20181255]
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We describe herein a fundamentally new visible light-driven homolytic C-C bond breaking mode for the generation of acyl radicals from C2-aryl-substituted benzothiazolines. The reactive species can be used as versatile synthons for formal radical alkylation, alkenylation, and alkynylation reactions.
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