Journal
ORGANIC LETTERS
Volume 21, Issue 14, Pages 5742-5746Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02149
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Funding
- National Natural Science Foundation of China [21772016]
- Jiangsu Province Funds for Distinguished Young Scientists [BK20160005]
- Shanghai Municipal Education Commission [2019-01-07-00-10-E00072]
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A palladium-catalyzed cyclizative phosphorylation reaction of (Z)-1-iodo-1,6-diene with diethyl H-phosphonate is developed, which provides facile access to unsaturated six-membered heterocycles bearing an alkyl-phosphonate group. The key step of this process is the efficient capture of the involved alkyl-Pd(II) species by H-phosphonate with the help of CsF, followed by reductive elimination of alkyl-Pd(II)-P(O)(OEt)(2). Moreover, this reaction is successfully extended to H-thionophosphonate.
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