Journal
ORGANIC LETTERS
Volume 21, Issue 17, Pages 6597-6602Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01951
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Funding
- Natural Science Foundation of China [21772003]
- BHP Billiton
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We describe an operationally simple transition-metal-free borylation of alkyl iodides. This method uses commercially available diboron reagents as the boron source and exhibits excellent functional group compatibility. Furthermore, a diverse range of primary and secondary alkyl iodides could be effectively transformed to the corresponding alkylboronates in excellent yield. Mechanistic investigations suggest that this borylation reaction proceeds through a single-electron transfer mechanism featuring the generation of an alkyl radical intermediate.
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