4.7 Article

Preparation and thermal energy storage studies of CH3COONa•3H2O-KCl composites salt system with enhanced phase change performance

Journal

APPLIED THERMAL ENGINEERING
Volume 102, Issue -, Pages 708-715

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.applthermaleng.2016.04.029

Keywords

Phase change material (PCM); CH3COONa center dot 3H(2)O-KCl composites salt system; Al2O3 nanoparticles; Nucleating agent; Supercooling

Funding

  1. National Science Foundation for Qaidam Saline Lake Chemical Engineering Science of China [U1407105]
  2. Natural Science Foundation of Qinghai province of China [2015-ZJ-930Q]

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The phase change performance of the CH3COONa center dot 3H(2)O-KCl composites salt system with Al2O3 nanoparticles and carboxyl methyl cellulose (CMC) were investigated in this paper. The CH3COONa center dot 3H(2)O-KCl composite salt system was prepared by adding KCI (at 2, 4, 6, 8, and 10 wt.%) to CH3COONa center dot 3H(2)O, respectively. Al2O3 nanoparticles were proposed as the nucleating agent and CMC was selected as a thickening agent for the CH3COONa center dot 3H(2)O-8 wt.%KCl composites salt system. The results show CH3COONa.3H(2)O-8 wt.%KCl composites salt system with 1 wt.% Al2O3 nanoparticles and 4 wt.% CMC, in which almost no supercoiling phenomenon occurs. After 50 cycles of the melting-freezing cycle test, aluminum oxide is uniformly dispersed in SAT composites matrix, the latent heat remained constant at about 232.29 J/g. The maximum deviations of latent heat of composites CH3COONa center dot 3H(2)O-8 wt.%KCl with 1 wt.% Al2O3 nanoparticles and 4 wt.% CMC before and after the fifty-run-recycling test are only 3.6%. (C) 2016 Elsevier Ltd. All rights reserved.

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