XPS analysis of the surface chemistry of sulfuric acid-treated kaolinite and diaspore minerals with flotation reagents

Kaolinite is one of the main associated minerals (gangue) in the processing of diasporic bauxites. Sulfuric acid pretreatment has been shown to have an improving effect on kaolinite-diaspore flotation separation, but the mechanism underpinning this effect is not well known. This study reports the surface chemistry of acid-treated kaolinite and diaspore in the presence of flotation reagents (sodium hexametaphosphate (SHMP) as a depressant and dodecylamine hydrochloride (DAH) as a collector) using X-ray photoelectron spectroscopy (XPS) analysis and zeta potential determinations. Quantitative XPS analysis revealed that the Al/Si atomic ratio on the kaolinite surface was reduced after the acid treatment. Compared with natural kaolinite, acid-treated kaolinite showed weakened adsorption properties for SHMP. Consequently, there was an enhanced DAH adsorption on the acid-treated kaolinite. High-resolution XPS analysis showed formations of unsaturated Al components on the diaspore surface after the acid treatment, which were ready to interact with phosphite groups of SHMP to depress diaspore in kaolinite flotation. Zeta potential studies also confirmed extended SHMP adsorption on acid-treated diaspore in comparison with the natural mineral. These findings form a firm knowledge for interpreting the application of kaolinite and diaspore in many adsorption studies, including the efficient separation between kaolinite and diaspore.