Modification of g-C3N4 nanosheets by carbon quantum dots for highly efficient photocatalytic generation of hydrogen

Carbon quantum dots (CQDs) were deposited onto graphite-like carbon nitride nanosheets (CNNS) to form CNNS/CQDs composites. The prepared CNNS/CQDs composites exhibit much higher photocatalytic activity under visible light irradiation than pure CNNS do. The CNNS/CQDs-7 sample displays the highest photocatalytic performance, with H-2 production rate of 116.1 mu mol h(-1), which is three times of that over pure CNNS (37.8 mu mol h(-1)). Photoluminescence spectroscopy and photoelectrochemical (PEC) analysis reveal that the CQDs are favorable for trapping electrons and promoting the separation of photogenerated electron-hole pairs in CNNS. A possible photocatalytic mechanism of the enhanced photocatalytic performance for H-2 generation over CNNS/CQDs will be proposed in this paper. (C) 2016 Elsevier B.V. All rights reserved.