4.8 Article

Efficient Electrogenerated Chemiluminescence of Pyrrolopyrrole Aza-BODIPYs in the Near-Infrared Region with Tripropylamine: Involving Formation of S2 and T2 States

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 141, Issue 30, Pages 11791-11795

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b05245

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Funding

  1. Japan Society for the Promotion of Science (JSPS) through its JSPS KAKENHI [JP 18K05176]

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Efficient electrogenerated chemiluminescences (ECLs) of three pyrrolopyrrole aza-BODIPYs in the near-infrared region by using tripropylamine as a coreactant are reported. Kinetic analysis based on Marcus theory indicates the direct formation of S-2 and T-2 states through the electron transfer reaction, which affects the ECL efficiencies.

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